太湖沉积物中重金属的地球化学形态及特征分析   总被引：24，自引：2，他引：22  

袁旭音  王爱华  许乃政 《地球化学》2004,33(6):611-618

用连续提取法分析了太湖沉积物5种重金属的地球化学形态,对地球化学形态的组成和地理特征进行了分析研究.重金属地球化学形态配分的共同特点是可交换态最低,残渣态最高.两种形态中Cd的可交换态最高,Cr的残渣态最高,可交换态最低.Cd的碳酸盐态较高,Cr的最低;Pb、Cd的Fe-Mn氧化态较高,Cu的偏低;Cu的有机态最高,Cd的最低;Zn的地球化学形态比例大都处于中间.地域上变化较大的元素是Cd和Cu,变化不明显的元素有Pb和Zn.化学成分中Fe2O3、MnO与重金属地球化学形态的相关性最好,TOC与Cu的形态相关系数最高.综合对比分析表明,太湖沉积物重金属的生物有效性以Cd为最高,其次为Pb.  相似文献   

南梁煤矿多煤层开采地下水系统演化规律     

白阳  齐跃明  项敏  苏磊  马仪鹏  兰璇  苏成志 《地质科技情报》2022,41(1):183-192

煤层开采对所在矿区地下水系统有着重要影响.以往研究单煤层开采对地下水系统的影响较多,而对多煤层的影响研究甚少,特别对于我国西部缺水矿区.以南梁煤矿为例,运用地下水系统演化理论和岩石力学模拟等,对该矿井水文地质结构、矿井涌水变化规律、矿井地下水流场演变、矿井地下水化学成分变化等方面进行了综合分析研究,重构了多煤层开采条件...  相似文献   

The thermal structure and the location of the snow line in the protosolar nebula: Axisymmetric models with full 3-D radiative transfer     

M. Min  C.P. Dullemond  C. Dominik 《Icarus》2011,212(1):416-426

The precise location of the water ice condensation front (‘snow line’) in the protosolar nebula has been a debate for a long time. Its importance stems from the expected substantial jump in the abundance of solids beyond the snow line, which is conducive to planet formation, and from the higher ‘stickiness’ in collisions of ice-coated dust grains, which may help the process of coagulation of dust and the formation of planetesimals. In an optically thin nebula, the location of the snow line is easily calculated to be around 3 AU, subject to brightness variations of the young Sun. However, in its first 5-10 myr, the solar nebula was optically thick, implying a smaller snowline radius due to shielding from direct sunlight, but also a larger radius because of viscous heating. Several models have attempted to treat these opposing effects. However, until recently treatments beyond an approximate 1 + 1D radiative transfer were unfeasible. We revisit the problem with a fully self-consistent 3D treatment in an axisymmetric disk model, including a density-dependent treatment of the dust and ice sublimation. We find that the location of the snow line is very sensitive to the opacities of the dust grains and the mass accretion rate of the disk. We show that previous approximate treatments are quite efficient at determining the location of the snow line if the energy budget is locally dominated by viscous accretion. Using this result we derive an analytic estimate of the location of the snow line that compares very well with results from this and previous studies. Using solar abundances of the elements we compute the abundance of dust and ice and find that the expected jump in solid surface density at the snow line is smaller than previously assumed. We further show that in the inner few AU the refractory species are also partly evaporated, leading to a significantly smaller solid state surface density in the regions where the rocky planets were formed.  相似文献   

Atypical size selection of captive school prawns,Metapenaeus macleayi,by three recreational fishing gears in south‐eastern Australia     

Matt K. Broadhurst  Russell B. Millar  Damian J. Young  Michael E. L. Wooden  Stuart Rowland 《新西兰海洋与淡水研究杂志》2013,47(5):755-766

Three manipulative experiments were done to estimate the selectivity of conventional and new sizes and configurations of mesh for school prawns, Metapenaeus macleayi, in three south‐eastern Australian recreational fishing gears (haul, push, and scoop nets). The treatment meshes examined were: (1) conventional‐sized, diamond‐shaped mesh used in all gears (20 mm in scoop nets and 30 mm in push and haul nets); (2) 30 mm in scoop nets; and (3) 40‐mm diamond‐ and (4) 23‐mm square‐shaped mesh in all gears. In all experiments, known quantities of school prawns (6–24 mm carapace length (CL)) were placed in purpose‐built enclosures, monitored to ensure no experimental‐induced stress (as measured by changes in L‐lactate in their haemolymph) and the replicate treatments of the various gear configurations deployed. Escapees from the various treatment nets were collected from the enclosures using fine‐meshed nets. Logistic selection curves were derived for all treatment nets and specific comparisons made within and among gears. All nets had 50% retention lengths (L₅₀) comparable to other penaeid‐catching gears with similar mesh sizes, but most had selection ranges (SRs) that were atypically inflated. The large SRs were attributed to a combination of factors that included the mesh geometry and towing speed of the gears and the behaviour of school prawns. The 20‐mm scoop net had the smallest selection parameters, retaining >99% of individuals larger than 13 mm CL. Mesh size in this gear would need to be increased to at least 30 mm to allow some maturing prawns (>18 mm CL) to escape.  相似文献   

Determination of cosmogenic ³²P and ³³P in environmental samples     

CHEN Min  YANG Zhi  ZHANG Lei  QIU Yusheng  MA Qiang  HUANG Yipu 《海洋学报(英文版)》2013,32(6):18-25

Understanding phosphorus dynamics in marine environment is of great importance, and appropriate tracers for phosphorus cycling in oceans are invaluable. In this study, two methods were developed for extraction, purification, and determination of naturally occurring 32P and 33P in rainwater, marine plankton and sediments using both a low-level beta counter (LBC) and an ultra-low-level liquid scintillation spectrometer (LSS). Blanks, chemical yields and counting efficiencies were quantified for both methods. The chemical purification of 32P and 33P separated by both procedures was validated by their decay curves. The absorber thickness of aluminum for LBC was assessed as 39.2 mg/cm 2 . 32P and 33P specific activities in some rain samples were determined by both methods and showed good consistent results. The advantage of the LSS over the LBC is apparent in its high counting efficiency and in determining samples with high concentration of stable phosphorus. However, when measuring environmental samples with low concentration of stable phosphorus, such as rainwater, both methods can be used and each has its distinct advantage.  相似文献   

蓝隐藻藻蓝蛋白结构与功能稳定性研究   总被引：1，自引：0，他引：1  

李文军  陈敏 《海洋科学》2013,37(7):33-40

以蓝隐藻(Chroomonas placiodea)藻蓝蛋白 PC-645为材料,通过改变环境 pH 和尿素质量浓度,监测其变性和复性过程中特征荧光谱和吸收谱的动力学变化,以期了解隐藻藻蓝蛋白的色基和蛋白结构稳定性及其与功能的关系。结果表明, PC-645在很宽的 pH 范围和一定质量浓度的尿素中维持结构和功能的稳定,空间结构具有很强的柔性。pH诱导的 PC-645蛋白构象与功能变化可分为3个不同的区段。(1)稳定区(pH 3.5~7)：吸收和荧光光谱都比较稳定,显示蛋白质构象和功能在此区域都保持正常。(2)次稳定区(pH 7~10)：光吸收依然保持平稳,亚基内部的色基的状态和疏水微环境都没有改变,但荧光传递效率降低,可能是由亚基表面局部构象变化、解离(四级结构变化)或者色素基团间的空间距离变化引起。(3)不稳定区(pH<3.5和 pH>10),吸光度和荧光强度都呈快速下降,色基在近紫外和可见光区的吸收峰位变动,蛋白构象处于快速崩溃期。PC-645在酸性条件下的稳定性高于在碱性环境下,是与隐藻藻蓝蛋白所处的特殊环境及生理功能相适应的。  相似文献   

Accurate GPS measurement of the location and orientation of a floating platform     

G. H. Purcell Jr.  L. E. Young  S. Kornreich Wolf  T. K. Meehan  C. B. Duncan  S. S. Fisher 《Marine Geodesy》2013,36(3-4):255-264

Abstract

This article describes the design and initial tests of the GPS portion of a system for making seafloor geodesy measurements. In the planned system, GPS antennas on a floating platform will be used to measure the location of an acoustic transducer, attached below the platform, which interrogates an array of transponders on the seafloor. Since the GPS antennas are necessarily some distance above the transducer, a short‐baseline GPS interferometer consisting of three antennas is used to measure the platform's orientation.

A preliminary test of several crucial elements of the system was performed at the Scripps Institution of Oceanography (SIO) in December 1989. The test involved a fixed antenna on the pier and a second antenna floating on a buoy about 80 m away. GPS measurements of the vertical component of this baseline, analyzed independently by two groups using different software, agree with each other and with an independent measurement within a centimeter.

The first test of an integrated GPS/acoustic system took place in the Santa Cruz Basin off the coast of southern California in May 1990. In this test a much larger buoy, designed and built at SIO, was equipped with three GPS antennas and an acoustic transducer that interrogated a transponder on the ocean floor. Preliminary analysis indicates that the horizontal position of the transponder can be determined with a precision of about a centimeter. Further analysis will be required to investigate the magnitude of systematic errors.  相似文献   

Nitrogen budget of the eelgrass, Zostera marina in a bay system on the south coast of Korea     

Sang Rul Park  Young Kyun Kim  Seung Hyeon Kim  Kun-Seop Lee 《Ocean Science Journal》2013,48(4):301-310

Above- and below-ground productivities and tissue N content were measured monthly to quantify N incorporation to sustain eelgrass growth in Koje Bay on the south coast of Korea from January to December 2002. N acquisition was also estimated through measurements of N uptake kinetics, tissue biomass, and in situ inorganic N concentrations in water column and sediments. Above- and below-ground productivities were highest in summer and lowest in late fall and winter. Leaf tissue N content was highest in December and lowest in July, while rhizome tissue N content was highest in October and lowest in April. Estimated monthly N incorporation by leaf tissues based on the leaf productivity and N content ranged from 0.4 g N m^?2 month^?1 in November to 2.0 g N m^?2 month^?1 in May. N incorporation by below-ground tissues ranged from 0.1 g N m^?2 month^?1 in February to 0.2 g N m^?2 month^?1 in October. Annual whole plant N incorporation was 14.5 g N m^?2 y^?1, and N incorporation by leaf tissues accounted for about 87 % of total N incorporation. Maximum uptake rate (V _max ) and half saturation constant (K _m ) of leaf NH₄ ⁺ uptake were significantly lower than those of root NH₄ ⁺ uptake. Above- and below-ground biomass ranged from 20.8 g DW m^?2 and 8.6 g DW m^?2 in winter to 350.0 g DW m^?2 and 81.3 g DW m^?2 in spring, respectively. NH₄ ⁺ concentrations varied from 0.2 to 4.3 mM in water column and from 93.0 to 551.7 mM in sediment pore water. Based on these measurements, annual N acquisition by root tissues contributed slightly higher than that by leaf tissues to total plant N acquisition. During winter, monthly leaf N acquisition was lower than monthly leaf N incorporation. This implies that Z. marina has internal nitrogen retention system to offset the shortage and excess of nitrogen.  相似文献   

海洋细菌脂肪酸的气相色谱分析     

徐敏  王静  柴子涵  牟海津 《海洋科学》2013,37(2):76-83

以副溶血性弧菌VP-X-3为试验对象,利用气相色谱技术分析了其细胞脂肪酸的组成和含量,以色谱峰的数量、色谱峰高及脂肪酸含量作为评价指标,探讨了不同的皂化和甲酯化条件对细菌细胞脂肪酸测定结果的影响。结果表明:皂化和甲酯化条件都对细胞脂肪酸的组成和含量产生一定的影响。较低温度皂化处理利于增加色谱峰数量和色谱峰高。甲酯化温度过高容易破坏脂肪酸,尤其是长链脂肪酸和不饱和脂肪酸的结构。高温甲酯化条件下,时间越长,甲酯化效果越差。试验得到较为理想的气相色谱前处理条件:2 mol/L NaOH-甲醇溶液2 mL,70℃水浴10 min;10%(V/V)H2SO4-甲醇溶液2 mL,70℃水浴15 min。此条件下的色谱峰的数量多达29种,色谱峰高明显高于其他处理条件下的峰高。  相似文献   

南海表层沉积硅藻的分布及其与环境因子的关系     

孙美琴  蓝东兆  付萍  陈敏  叶友权 《台湾海峡》2013,32(1):46-51

通过对取自南海62个站位的表层沉积物样品,进行了硅藻、沉积物粒度分析,查明了研究海区硅藻的种类组成及分布特点,共鉴定到硅藻56属的235个种和变种、变型.种类以热带外洋种为优势,如Azpeitia nodulifer、Roperia tesselata、Azpeitia africanus、Hemidiscus cuneiformis、Nitzschia marine 等,伴有一定量的热带—亚热带近岸种和广布种如Paralia sulcata、Thalassiosira excentrica、Cyclotella stylorum、Thalassionema nitzschioides、Thalassiothrix longissoma等.总体上,南海硅藻丰度变化呈现从陆架向陆坡至海盆递增的趋势.研究海区硅藻种类组成与临近的菲律宾海域相似程度最大,其次是东海、太平洋东北部海域.对影响南海表层沉积硅藻分布的主要因素进行了探讨,南海表层沉积硅藻主要受海底地质地貌、沉积速率、水动力条件和水文气候条件等的影响较大,硅藻的分布往往是这些因素综合作用的结果.  相似文献